An unprecedented six-fold anion-type chiral diamondoid-like eight-coordinate Cd(II) coordination polymer with a second-order nonlinear optical effect

被引:104
作者
Chen, ZF
Xiong, RG
Abrahams, BF [1 ]
You, XZ
Che, CM
机构
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia
[3] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 17期
关键词
D O I
10.1039/b105130j
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of Cd(OH)(2) with 3,3'-azodibenzoic acid affords an unprecedented anionic chiral diamondoid network, bis(3,3'-azodibenzoate)cadmium.(H2NMe2)(NH4) which contains eight-coordinate cadmium and displays strong SHG response and enantioselectivity for organic amines.
引用
收藏
页码:2453 / 2455
页数:3
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