A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization

被引：231

作者：

Gutekunst, Will R. ^{[1
]}

Hawker, Craig J. ^{[1
,2
]}

机构：

[1] Univ Calif Santa Barbara, Dept Mat, Mat Res Lab, Santa Barbara, CA 93106 USA

[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2015年 / 137卷 / 25期

基金：

美国国家科学基金会;

关键词：

MONOMER; COPOLYMERS; OLIGOMERS; HYDROLYSIS; MECHANISM;

D O I：

10.1021/jacs.5b04940

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization of unstrained macrocyclic structures. Central to this approach is the development of a small molecule polymerization trigger which when coupled with a diverse range of sequence-defined units allows for the controlled, directional synthesis of sequence controlled polymers.

引用

页码：8038 / 8041

页数：4

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