Synthetic equivalents of alkynyl and propargyl radicals

被引：35

作者：

Boutillier, P ^{[1
]}

Zard, SZ ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, Organ Synth Lab, F-91128 Palaiseau, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 14期

关键词：

D O I：

10.1039/b101751i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radicals derived from beta -ketoesters can, depending on the position of the unpaired electron, represent synthetic equivalents to the high energy and elusive alkynyl radicals or to the stabilised and relatively unreactive propargyl radicals by application of the xanthate transfer reaction followed by nitrosative cleavage of the corresponding isoxazolinones.

引用

页码：1304 / 1305

页数：2

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