Photoinduced reactions of tertiary amines with [60]fullerene; Addition of an alpha-C-H bond of amines to [60]fullerene

被引：65

作者：

Liou, KF ^{[1
]}

Cheng, CH ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 300,TAIWAN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 12期

关键词：

D O I：

10.1039/cc9960001423

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photochemical reaction of [60]fullerene with RNMe(2) (R = Ph and Me) gives an adduct (1, R = Ph; 2, R = Me) formed by the addition of an alpha-C-H bond of the amine to a 6/6 ring junction of [60]fullerene; 2 on further irradiation in the presence of [60]fullerene is converted to the pyrrolidine derivative 3 and 1,2-H2C60.

引用

页码：1423 / 1424

页数：2

共 19 条

[1] ELECTRON-TRANSFER TO TRIPLET C-60
ARBOGAST, JW
FOOTE, CS
KAO, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) : 2277 - 2279
[2] HYDROGENATION OF BUCKMINSTERFULLERENE C-60 VIA HYDROZIRCONATION - A NEW WAY TO ORGANOFULLERENES
BALLENWEG, S
GLEITER, R
KRATSCHMER, W
[J]. TETRAHEDRON LETTERS, 1993, 34 (23) : 3737 - 3740
[3] CHARGE RECOMBINATION REACTIONS IN PHOTOEXCITED C-60-AMINE COMPLEXES STUDIED BY PICOSECOND PUMP-PROBE SPECTROSCOPY
GHOSH, HN
PAL, H
SAPRE, AV
MITTAL, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) : 11722 - 11727
[4] C60H2 - SYNTHESIS OF THE SIMPLEST C60 HYDROCARBON DERIVATIVE
HENDERSON, CC
CAHILL, PA
[J]. SCIENCE, 1993, 259 (5103) : 1885 - 1887
[5] GLOBE-TROTTING HYDROGENS ON THE SURFACE OF THE FULLERENE COMPOUND C60H6(N(CH2CH2)2O)6
HIRSCH, A
LI, QY
WUDL, F
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (10): : 1309 - 1310
[6] TRANS-STILBENE AMINE EXCIPLEXES - BEHAVIOR OF THE EXCIPLEX, SOLVENT-SEPARATED RADICAL ION-PAIR, AND FREE-RADICAL IONS
HUB, W
SCHNEIDER, S
DORR, F
OXMAN, JD
LEWIS, FD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) : 708 - 715
[7] PHOTOCHEMICAL-REACTION OF C-60 IN THE PRESENCE OF TRIETHYLAMINE IN TOLUENE
KAJII, Y
TAKEDA, K
SHIBUYA, K
[J]. CHEMICAL PHYSICS LETTERS, 1993, 204 (3-4) : 283 - 286
[8] PHOTOINDUCED INTERMOLECULAR AND INTRAMOLECULAR ELECTRON-TRANSFER REACTIONS OF [60]FULLERENE AND A TERTIARY AMINE - FORMATION OF THE CYCLOADDUCT N-ETHYL-TRANS-2',5'-DIMETHYLPYRROLIDINO[3',4'/1,2][60]FULLERENE
LAWSON, GE
KITAYGORODSKIY, A
MA, B
BUNKER, CE
SUN, YP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (21) : 2225 - 2226
[9] ADDITION OF AZOMETHINE YLIDES TO C-60 - SYNTHESIS, CHARACTERIZATION, AND FUNCTIONALIZATION OF FULLERENE PYRROLIDINES
MAGGINI, M
SCORRANO, G
PRATO, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9798 - 9799
[10] ULTRAFAST PHOTOINDUCED ELECTRON-TRANSFER TO C60
SENSION, RJ
SZARKA, AZ
SMITH, GR
HOCHSTRASSER, RM
[J]. CHEMICAL PHYSICS LETTERS, 1991, 185 (3-4) : 179 - 183

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