HYDROGENATION OF BUCKMINSTERFULLERENE C-60 VIA HYDROZIRCONATION - A NEW WAY TO ORGANOFULLERENES

被引:102
作者
BALLENWEG, S
GLEITER, R
KRATSCHMER, W
机构
[1] MAX PLANCK INST NUCL PHYS,POSTFACH 103980,W-6900 HEIDELBERG 1,GERMANY
[2] UNIV HEIDELBERG,INST ORGAN CHEM,W-6900 HEIDELBERG,GERMANY
关键词
D O I
10.1016/S0040-4039(00)79214-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Hydrogenation of buckminsterfullerene C60 has been achieved via reaction with (eta5-C5H5)2Zr(H)Cl (hydrozirconation). Hydrolysis of the intermediate C60 zirconium(IV) complex, [(eta5-C5H5)2ZrCl]nC60Hn with n=1,2,3 yielded a mixture of C60H2n and unreacted C60, from which C60H2 has been isolated through preparative high performance liquid chromatography (HPLC).
引用
收藏
页码:3737 / 3740
页数:4
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