One-step synthesis of water-soluble gold nanoparticles/polyaniline composite and its application in glucose sensing

被引:43
作者
Ma, Y [1 ]
Li, N [1 ]
Yang, C [1 ]
Yang, XR [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China
基金
中国国家自然科学基金;
关键词
nanoparticles; 3-aminophenylboronic acid; poly (vinyl alcohol); glucose; biosensors;
D O I
10.1016/j.colsurfa.2005.04.030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Water-soluble gold nanoparticles/polyaniline nanocomposite was synthesized by using 3-aminophenylboronic acid (3-APBA) as reductive and protective reagent. The polyhydroxy compound poly (vinyl alcohol) (PVA) was used as disperser based on the covalent bond interaction between the boronic acid and diol group. Transmission electron microscopy (TEM) and UV-vis absorbance spectroscopy were used to characterize the nanoparticles. The results showed that the water-soluble gold nanoparticles/polyaniline nanocomposite could be synthesized by using 3-APBA as reductive reagent in the presence of PVA, which was used as disperser. The particle size could be tuned by changing the concentration of PVA. The nanocomposite prepared in this way could sense glucose based on the competitive between reaction of 3-APBA and PVA, and that of 3-APBA, which indicated that this nanocomposite could be used as sensitive optical probe for the detection of glucose. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 6
页数:6
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