Transistor Paint: High Mobilities in Small Bandgap Polymer Semiconductor Based on the Strong Acceptor, Diketopyrrolopyrrole and Strong Donor, Dithienopyrrole

被引：150

作者：

Nelson, Toby L. ^{[1
]}

Young, Tomasz M. ^{[1
]}

Liu, Junying ^{[1
]}

Mishra, Sarada P. ^{[1
]}

Belot, John A. ^{[1
]}

Balliet, Courtney L. ^{[1
]}

Javier, Anna E. ^{[1
]}

Kowalewski, Tomasz ^{[1
]}

McCullough, Richard D. ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

来源：

ADVANCED MATERIALS | 2010年 / 22卷 / 41期

基金：

美国国家科学基金会;

关键词：

FIELD-EFFECT TRANSISTORS; ALTERNATING COPOLYMERS; ORGANIC SEMICONDUCTORS; MOLECULAR DESIGN;

D O I：

10.1002/adma.201001599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A narrow bandgap, strong donor-acceptor polymer semiconductor is presented. This "transistor paint" material exhibits hole mobilities as high as 0.41 cm(2)/Vs. Importantly, the semiconductor yields high reproducible mobility values of 0.28 cm(2)/Vs +/- 0.019 for a range of channel lengths when measured from several transistors on different days.

引用

页码：4617 / 4621

页数：5

共 41 条

[11] Stable polythiophene semiconductors incorporating thieno[2,3-b]thiophene [J].

Heeney, M ;

Bailey, C ;

Genevicius, K ;

Shkunov, M ;

Sparrowe, D ;

Tierney, S ;

McCulloch, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (04) :1078-1079

[12] Synthesis, Characterization, and Photovoltaic Properties of a Low Band Gap Polymer Based on Silole-Containing Polythiophenes and 2,1,3-Benzothiadiazole [J].

Hou, Jianhui ;

Chen, Hsiang-Yu ;

Zhang, Shaoqing ;

Li, Gang ;

Yang, Yang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (48) :16144-+

[13] New ambipolar organic semiconductors. 2. Effects of electron acceptor strength on intramolecular charge transfer photophysics, highly efficient electroluminescence, and field-effect charge transport of phenoxazine-based donor-acceptor materials [J].

Kulkami, Abhishek P. ;

Zhu, Yan ;

Babel, Amit ;

Wu, Pei-Tzu ;

Jenekhe, Samson A. .

CHEMISTRY OF MATERIALS, 2008, 20 (13) :4212-4223

[14] Solubility- and temperature-driven thin film structures of polymeric thiophene derivatives for high performance OFET applications [J].

LeFevre, Scott W. ;

Bao, Zhenan ;

Ryu, Chang Y. ;

Siegel, Richard W. ;

Yang, Hoichang .

ORGANIC FIELD-EFFECT TRANSISTORS VI, 2007, 6658

[15] Polyindolo[3,2-b]carbazoles:: A new class of p-channel semiconductor polymers for organic thin-film transistors [J].

Li, Yuning ;

Wu, Yiliang ;

Ong, Beng S. .

MACROMOLECULES, 2006, 39 (19) :6521-6527

[16] Theory of magnetoelectric coupling in 2-2-type magnetostrictive/piezoelectric composite film with texture [J].

Liu, Chao-Qian ;

Fei, Wei-Dong ;

Li, Wei-Li .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2008, 41 (12)

[17] Highly disordered polymer field effect transistors:: N-alkyl dithieno[3,2-b:2′,3′-d]pyrrole-based copolymers with surprisingly high charge carrier mobilities [J].

Liu, Junying ;

Zhang, Rui ;

Sauve, Genevieve ;

Kowalewski, Tomasz ;

McCullough, Richard D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (39) :13167-13176

[18] Transistor Paint: Environmentally Stable N-alkyldithienopyrrole and Bithiazole-Based Copolymer Thin-Film Transistors Show Reproducible High Mobilities without Annealing [J].

Liu, Junying ;

Zhang, Rui ;

Osaka, Itaru ;

Mishra, Sarada ;

Javier, Anna E. ;

Smilgies, Detlef-M. ;

Kowalewski, Tomasz ;

McCullough, Richard D. .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (21) :3427-3434

[19]

Loewe RS, 1999, ADV MATER, V11, P250, DOI 10.1002/(SICI)1521-4095(199903)11:3<250::AID-ADMA250>3.0.CO

[20]

2-J

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