Chelating diamide based rate enhancement of intramolecular alkene hydroaminations catalyzed by a neutral Sc(III) complex

被引：106

作者：

Kim, JY ^{[1
]}

Livinghouse, T ^{[1
]}

机构：

[1] Montana State Univ, Dept Chem, Bozeman, MT 59717 USA

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 20期

关键词：

D O I：

10.1021/ol051574h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

graph Neutral scandium amido complexes are viable catalysts for intramolecular alkene hydroamination. Catalytic activity is strongly coupled to the electronic character of the ScIII(Ill) ligand environment with chelating diamide coordination providing a precatalyst possessing substantially improved activity and superb distereoselectivity in the synthesis of trans-2,5-disubstituted pyrrolidines.

引用

页码：4391 / 4393

页数：3

共 27 条

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