Cr poisoning suppression in solid oxide fuel cells using LaNi(Fe)O3 electrodes

被引:98
作者
Komatsu, T [1 ]
Arai, H
Chiba, R
Nozawa, K
Arakawa, M
Sato, K
机构
[1] NTT Corp, Energy & Environm Syst Lab, Atsugi, Kanagawa 2430198, Japan
[2] Nagaoka Univ Technol, Dept Environm Engn, Nagaoka, Niigata 9402188, Japan
关键词
D O I
10.1149/1.2130309
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We have investigated the effect of Cr poisoning on various cells which consist of either LaNi0.6Fe0.4O3 (LNF) or La0.8Sr0.2MnO3 (LSM) as a cathode and either yttria- stabilized zirconia (YSZ) or alumina- doped scandia stabilized zirconia (SASZ) as the electrolyte. It was found that the cathodic overvoltage was almost the same for cells with LNF cathodes, either in the presence or absence of Cr- containing alloy (Inconel 600). LSM cathodes in the presence of Inconel 600 exhibited a very steep increase in voltage curves after applying the current. These results indicate that the LNF cathode is electrochemically stable for Cr poisoning compared with the LSM cathode. (c) 2005 The Electrochemical Society.
引用
收藏
页码:A9 / A12
页数:4
相关论文
共 10 条
[1]   Interaction between chromia forming alloy interconnects and air electrode of solid oxide fuel cells [J].
Badwal, SPS ;
Deller, R ;
Foger, K ;
Ramprakash, Y ;
Zhang, JP .
SOLID STATE IONICS, 1997, 99 (3-4) :297-310
[2]   CHARACTERIZATION OF MNCRO3 AND CRMNO4 [J].
CHAMBERLAND, BL ;
KAFALAS, JA ;
GOODENOUGH, JB .
INORGANIC CHEMISTRY, 1977, 16 (01) :44-46
[3]   An investigation of LaNi1-xFexO3 as a cathode material for solid oxide fuel cells [J].
Chiba, R ;
Yoshimura, F ;
Sakurai, Y .
SOLID STATE IONICS, 1999, 124 (3-4) :281-288
[4]   Deposition of chromium species at Sr-doped LaMnO3 electrodes in solid oxide fuel cells I.: Mechanism and kinetics [J].
Jiang, SP ;
Zhang, JP ;
Apateanu, L ;
Foger, K .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (11) :4013-4022
[5]   APPLICABILITY OF HEAT RESISTING ALLOYS TO THE SEPARATOR OF PLANAR TYPE SOLID OXIDE FUEL-CELL [J].
KADOWAKI, T ;
SHIOMITSU, T ;
MATSUDA, E ;
NAKAGAWA, H ;
TSUNEIZUMI, H ;
MARUYAMA, T .
SOLID STATE IONICS, 1993, 67 (1-2) :65-69
[6]   Electrochemical properties of a SOFC cathode in contact with a chromium-containing alloy separator [J].
Matsuzaki, Y ;
Yasuda, I .
SOLID STATE IONICS, 2000, 132 (3-4) :271-278
[7]   Application of LaNi(Fe)O3 as SOFC cathode [J].
Orui, H ;
Watanabe, K ;
Chiba, R ;
Arakawa, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (09) :A1412-A1417
[8]  
Ruckdaschel R, 1997, ELEC SOC S, V97, P1273
[9]   THE SYSTEM MANGANESE OXIDE CR2O3 IN AIR [J].
SPEIDEL, DH ;
MUAN, A .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1963, 46 (12) :577-578
[10]   Suppression of chromium diffusion to an SOFC cathode from an alloy separator by a cathode second layer [J].
Taniguchi, S ;
Kadowaki, M ;
Yasuo, T ;
Akiyama, Y ;
Itoh, Y ;
Miyake, Y ;
Nishio, K .
DENKI KAGAKU, 1996, 64 (06) :568-574