Preparation of orthorhornbic LiMnO2 material via the sol-gel process

被引：45

作者：

Guo, ZP ^{[1
]}

Konstantinov, K ^{[1
]}

Wang, GX ^{[1
]}

Liu, HK ^{[1
]}

Dou, SX ^{[1
]}

机构：

[1] Univ Wollongong, Inst Supercond & Elect Mat, Wollongong, NSW 2500, Australia

来源：

JOURNAL OF POWER SOURCES | 2003年 / 119卷

关键词：

sol-gel; acid to metal ions ratio (R); orthorhombic LiMnO2;

D O I：

10.1016/S0378-7753(03)00237-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Orthorhombic LiMnO2 was synthesized via the sol-gel process using citric acid as a chelating agent. The effect of varying the molar acid to metal ions ratio (R) on the structural and electrochemical properties of the synthesized compound was studied. Samples with high R (R = 1, 2) contain large amount of MnO impurity phase, which is electrochemically inactive and thus is detrimental to the electrochemical activity of the electrode. Therefore, the acid to metal ions ratio "R" should not be high. Samples with low R (R = 0.5) exhibited a high initial capacity, above 190 mAh/g when cycled at a current density of 0.4 mA/cm(2) at room temperature. The ac impedance results show that the initial capacity was improved (compared with ss-o-LiMnO2) due to the smaller particle size and good homogeneity, which improves the Li+ diffusion in the cathode. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：221 / 225

页数：5

共 16 条

[11] Amorphous manganese oxyiodides exhibiting high lithium intercalation capacity at higher current density [J].

Kim, J ;

Manthiram, A .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 1999, 2 (02) :55-57

[12] Synthesis and electrochemical characteristics of spinel phase LiMn2O4-based cathode materials for lithium polymer batteries [J].

Sun, YK ;

Jin, SH .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (11) :2399-2404

[13] Lithium ion extraction from orthorhombic LiMnO2 in ammonium peroxodisulfate solutions [J].

Tang, WP ;

Kanoh, H ;

Ooi, K .

JOURNAL OF SOLID STATE CHEMISTRY, 1999, 142 (01) :19-28

[14] THE SPINEL PHASE OF LIMN2O4 AS A CATHODE IN SECONDARY LITHIUM CELLS [J].

TARASCON, JM ;

WANG, E ;

SHOKOOHI, FK ;

MCKINNON, WR ;

COLSON, S .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (10) :2859-2864

[15] LITHIUM INSERTION INTO MANGANESE SPINELS [J].

THACKERAY, MM ;

DAVID, WIF ;

BRUCE, PG ;

GOODENOUGH, JB .

MATERIALS RESEARCH BULLETIN, 1983, 18 (04) :461-472

[16]

Xia X, 2000, J NEW MAT ELECT SYST, V3, P327

← 1 2 →