Increasing the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) by ultraviolet irradiation

被引:88
作者
Lin, Yow-Jon [1 ]
Yang, Fu-Ming
Huang, Chi-Yen
Chou, Wei-Yang
Chang, Jay
Lien, Yi-Chun
机构
[1] Natl Changhua Univ Educ, Inst Photon, Changhua 500, Taiwan
[2] Natl Cheng Kung Univ, Inst Electroopt Sci & Engn4, Tainan 701, Taiwan
[3] Natl Changhua Univ Educ, Dept Phys, Changhua 500, Taiwan
关键词
D O I
10.1063/1.2777147
中图分类号
O59 [应用物理学];
学科分类号
摘要
The effects of ultraviolet (UV) irradiation on the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) (PEDOT:PSS) have been investigated in this study. Spectroscopic methods [x-ray photoelectron spectroscopy and Raman spectroscopy (532 nm excitation)] and electrical conductivity measurements were used to characterize the electrical conducting polymer PEDOT:PSS prepared by UV irradiation. The authors found that UV irradiation could lead to an increase in the work function and the enhancement of electrical conductivity of PEDOT:PSS, resulting from a decrease in the number of the charge-trapping-related defects and the formation of linear or expanded-coil conformation.
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页数:3
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