Decomposition of alkanethiols adsorbed on Au (111) at low temperature

被引：33

作者：

Kodama, C

Hayashi, T

Nozoye, H ^{[1
]}

机构：

[1] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 305, Japan

[2] Natl Inst Mat & Chem Res, Tsukuba, Ibaraki 3058565, Japan

来源：

APPLIED SURFACE SCIENCE | 2001年 / 169卷

关键词：

alkanethiols; self-assembled monolayers (SAMs); temperature programmed desorption (TPD);

D O I：

10.1016/S0169-4332(00)00664-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption and desorption of butanethiol (CH3(CH2)(3)SH: C4), hexanethiol (CH3(CH2)(5)SH:C6) and octanethiol (CH3(CH2)(7)SH: C8) on Au (1 1 1) under vacuum condition have been studied by temperature programmed desorption (TPD). Desorptions of thiolate radical species were observed for C6 and C8. Connecting the desorption temperatures of parent thiols from the first layer and that of hydrogen, we were able to find a condition for thiolate radicals to be desorbed from the surface. (C) 2001 published by Elsevier Science B.V.

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页码：264 / 267

页数：4

相关论文

共 12 条

[1] MOLECULAR ORDERING OF ORGANOSULFUR COMPOUNDS ON AU(111) AND AU(100) - ADSORPTION FROM SOLUTION AND IN ULTRAHIGH-VACUUM [J].

DUBOIS, LH ;

ZEGARSKI, BR ;

NUZZO, RG .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (01) :678-688

[2] SYNTHESIS, STRUCTURE, AND PROPERTIES OF MODEL ORGANIC-SURFACES [J].

DUBOIS, LH ;

NUZZO, RG .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1992, 43 :437-463

[3] THE ADSORPTION OF HYDROGEN-SULFIDE ON CLEAN AND SULFIDED AU(110) [J].

JAFFEY, DM ;

MADIX, RJ .

SURFACE SCIENCE, 1991, 258 (1-3) :359-375

[4] Molecular processes of adsorption and desorption of alkanethiol monolayers on Au(111) [J].

Kondoh, H ;

Kodama, C ;

Sumida, H ;

Nozoye, H .

JOURNAL OF CHEMICAL PHYSICS, 1999, 111 (03) :1175-1184

[5] Structure-dependent change of desorption species from n-alkanethiol monolayers adsorbed on Au(111):: Desorption of thiolate radicals from low-density structures [J].

Kondoh, H ;

Kodama, C ;

Nozoye, H .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (13) :2310-2312

[6] Physisorption and chemisorption of alkanethiols and alkyl sulfides on Au(111) [J].

Lavrich, DJ ;

Wetterer, SM ;

Bernasek, SL ;

Scoles, G .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (18) :3456-3465

[7] CHEMICAL-REACTIVITY STUDIES OF HYDROGEN-SULFIDE ON AU(111) [J].

LEAVITT, AJ ;

BEEBE, TP .

SURFACE SCIENCE, 1994, 314 (01) :23-33

[8] Thermal desorption spectroscopy of alkanethiol self-assembled monolayer on Au(111) [J].

Nishida, N ;

Hara, M ;

Sasabe, H ;

Knoll, W .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1996, 35 (11) :5866-5872

[9] FUNDAMENTAL-STUDIES OF THE CHEMISORPTION OF ORGANOSULFUR COMPOUNDS ON AU(111) - IMPLICATIONS FOR MOLECULAR SELF-ASSEMBLY ON GOLD SURFACES [J].

NUZZO, RG ;

ZEGARSKI, BR ;

DUBOIS, LH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) :733-740

[10] Characterization of organosulfur molecular monolayers on Au(111) using scanning tunneling microscopy [J].

Poirier, GE .

CHEMICAL REVIEWS, 1997, 97 (04) :1117-1127