Preparation and electrical properties of fine strontium titanate powder from titanium alkoxide in a strong alkaline solution

被引:31
作者
Kao, CF
Yang, WD
机构
[1] Department of Chemical Engineering, National Cheng Kung University
来源
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 1996年 / 38卷 / 1-2期
关键词
morphology; hydrolysis; condensation; titanyl acylate precursor;
D O I
10.1016/0921-5107(95)01512-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The particle size of the forming ceramic powder is related to the morphology of forming precipitated precursor. The rates of hydrolysis and condensation of titanyl acylate gel were slow because of the chelating action of acetic acid. Therefore, the particle size of the precursor gel was uniform and finer, and the formation rate of the powder was quicker. The powder obtained contained fine particles of size similar to 0.04 - 0.05 mu m and was readily sintered at 1423 - 1523 K. The dielectric constant and dissipation factor of strontium titanate were determined.
引用
收藏
页码:127 / 137
页数:11
相关论文
共 34 条
[11]   TINO2N-1 MAGNELI PHASE FORMATION IN SRTIO3 DIELECTRICS [J].
FUJIMOTO, M ;
WATANABE, M .
JOURNAL OF MATERIALS SCIENCE, 1985, 20 (10) :3683-3690
[12]  
HARTEL RW, 1986, BETTER CERAMICS CHEM, V2, P633
[13]  
Hennings D., 1991, Journal of the European Ceramic Society, V8, P107, DOI 10.1016/0955-2219(91)90116-H
[14]  
KAO CF, IN PRESS CERAM INT
[15]   FERROELECTRICS OF ULTRAFINE PARTICLE SIZE .1. SYNTHESIS OF TITANATE POWDERS OF ULTRAFINE PARTICLE SIZE [J].
KISS, K ;
MAGDER, J ;
VUKASOVI.MS ;
LOCKHART, RJ .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1966, 49 (06) :291-&
[16]  
KRIEGSMANN H, 1958, Z ELEKTROCHEM, V62, P1163
[17]   SOL-GEL CHEMISTRY OF TRANSITION-METAL OXIDES [J].
LIVAGE, J ;
HENRY, M ;
SANCHEZ, C .
PROGRESS IN SOLID STATE CHEMISTRY, 1988, 18 (04) :259-341
[18]   THE CHEMISTRY OF THE SOL-GEL PROCESS [J].
LIVAGE, J ;
SANCHEZ, C ;
HENRY, M ;
DOEUFF, S .
SOLID STATE IONICS, 1989, 32-3 :633-638
[19]   PREPARATION OF HIGH-PURITY SUBMICRON BARIUM TITANATE POWDERS [J].
MAZDIYAS.KS ;
DOLLOFF, RT ;
SMITH, JS .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1969, 52 (10) :523-&