Lipase-catalyzed syntheses of sugar esters in non-aqueous media

被引：73

作者：

Kobayashi, Takashi ^{[1
]}

机构：

[1] Kyoto Univ, Div Food Sci & Biotechnol, Grad Sch Agr, Sakyo Ku, Kyoto 6068502, Japan

来源：

BIOTECHNOLOGY LETTERS | 2011年 / 33卷 / 10期

关键词：

Lipase; Non-aqueous medium; Productivity; Sugar derivative; Sugar ester; CANDIDA-ANTARCTICA LIPASE; FATTY-ACID ESTERS; ENZYMATIC-SYNTHESIS; IONIC LIQUIDS; REGIOSELECTIVE ACYLATION; EQUILIBRIUM-CONSTANT; SELECTIVE ACYLATION; PHENOLIC-ACIDS; L-ALANYL; ESTERIFICATION;

D O I：

10.1007/s10529-011-0663-z

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

The lipase-catalyzed reaction is useful to obtain sugar esters with chemically defined structures and will contribute to the synthesis of sugar-based compounds by a chemo-enzymatic pathway. The synthesis of sugar esters in nonaqueous media has been attempted for a quarter century. To facilitate the reactions, they have been performed either in an organic solvent with/without a polar adjuvant or in an ionic liquid, or by using a hydrophobic sugar derivative. In this review, the following points are discussed: (1) various synthetic methods of sugar esters; (2) role of the solvents or adjuvants; and (3) improvement in the productivity.

引用

页码：1911 / 1919

页数：9

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