A study of a highly efficient resonance energy transfer between 7-N,N-diethylamino-4-methylcoumarin and 9-butyl-4-butylamino-1,8-naphthalimide

被引:27
作者
May, B [1 ]
Poteau, X [1 ]
Yuan, DW [1 ]
Brown, RG [1 ]
机构
[1] Univ Cent Lancashire, Ctr Photochem, Preston PR1 2HE, Lancs, England
关键词
D O I
10.1016/S0143-7208(99)00011-X
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The quenching of the fluorescence of 7-N,N-diethylamino-4-methylcoumarin by 9-butyl-4-butylamino-1,8-naphthalimide has been studied in a variety of solvents. The resulting Stern-Volmer plots are non-linear since both radiative and non-radiative energy transfer mechanisms are in operation. The latter is very efficient with rate constants > 10(12) dm(3) mol(-1) s(-1) and average donor-acceptor distances for the energy transfer of approximate to 2 nm. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
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页码:79 / 84
页数:6
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