Molecular Prussian Blue analogues:: synthesis and structure of cubic Cr4Co4(CN)12 and Co8(CN)12 clusters

被引：155

作者：

Heinrich, JL ^{[1
]}

Berseth, PA ^{[1
]}

Long, JR ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 11期

关键词：

D O I：

10.1039/a802351d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions between [M(H2O)(3)(tacn)](3+) (M = Cr, Co) and [Co(CN)3(tacn)] are demonstrated to produce the molecular box clusters [Cr4Co4(CN)(12)(tacn)(8)](12+) and [CO8(CN)(12)(tacn)(8)](12+) with core structures consisting of a single cubic unit excised from the Prussian Blue type framework.

引用

页码：1231 / 1232

页数：2

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