Ambipolar transistor properties of 2,2′-binaphthosemiquinones

被引:13
作者
Higashino, Toshiki [1 ]
Kumeta, Shohei [1 ]
Tamura, Sumika [1 ]
Ando, Yoshio [2 ]
Ohmori, Ken [2 ]
Suzuki, Keisuke [2 ]
Mori, Takehiko [1 ,3 ]
机构
[1] Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan
[2] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan
[3] JST, ACT C, Kawaguchi, Saitama 3320012, Japan
关键词
FIELD-EFFECT TRANSISTORS; HIGH-PERFORMANCE AMBIPOLAR; THIN-FILM TRANSISTORS; DONOR-ACCEPTOR POLYMERS; ORGANIC SEMICONDUCTORS; N-TYPE; INDIGO; ELECTRON; DIKETOPYRROLOPYRROLE; TRANSPORT;
D O I
10.1039/c4tc02467b
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Binaphthosemiquinones are proved to show ambipolar transistor properties. These compounds have characteristic blue colors owing to the small energy gaps, because the quinone part acts as an electron acceptor and the alkoxy group acts as an electron donor. Accordingly, these molecules have an analogous electronic structure to indigo. The crystal structure changes depending on the alkoxy groups, though these compounds generally have stacking structures.
引用
收藏
页码:1588 / 1594
页数:7
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