Preparation of hexacarbonyldicobalt-complexed 1,3-dioxa-2-silacycloheptynes

被引：10

作者：

Brook, MA ^{[1
]}

Urschey, J ^{[1
]}

Stradiotto, M ^{[1
]}

机构：

[1] McMaster Univ, Dept Chem, Hamilton, ON L8S 4M1, Canada

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 24期

关键词：

D O I：

10.1021/om980589z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between 2-butyne-1,4-diol-hexacarbonyldicobalt and a series of dichlorodialkylsilanes (R = Me, Et, CH=CH2, and Ph) in the presence of triethylamine results in the formation of the corresponding cobalt-complexed 1,3-dioxa-2-silacycloheptynes, 3-7, as the major products. Complexed silacyclononynes, 8 and 9, and a spirocyclic analogue 10, have also been prepared and characterized. The solid-state structures of 3 and 10 have been determined by X-ray diffraction studies.

引用

页码：5342 / 5346

页数：5

共 39 条

[1] Synthesis of linear oligomers of [1,3-diethynyl-2,4-bis(trimethylsilyl)cyclobutadiene]cyclopentadienylcobalt: Dimer to nonamer [J].

Altmann, M ;

Enkelmann, V ;

Beer, F ;

Bunz, UHF .

ORGANOMETALLICS, 1996, 15 (01) :394-399

[2] POLYMERS WITH COMPLEXED CYCLOBUTADIENE UNITS IN THE MAIN-CHAIN - THE FIRST EXAMPLE OF A THERMOTROPIC, LIQUID-CRYSTALLINE ORGANOMETALLIC POLYMER [J].

ALTMANN, M ;

BUNZ, UHF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (05) :569-571

[3]

Bassindale A. R., 1989, CHEM ORGANIC SILICON, V1, P839

[4] A NOVEL GLYCOL-SILICONE POLYMER [J].

BROOK, MA ;

KREMERS, CH ;

SEBASTIAN, T ;

YU, WF .

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS, 1989, 27 (07) :229-234

[5] Organometallic ''carbon chains'': They just keep getting longer! [J].

Bunz, UHF .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (09) :969-971

[6] SYNTHESIS OF THE FIRST REDOX-ACTIVE ORGANOMETALLIC POLYMERS CONTAINING CYCLOSILOXANES AS FRAMEWORKS [J].

CASADO, CM ;

CUADRADO, I ;

MORAN, M ;

ALONSO, B ;

LOBETE, F ;

LOSADA, J .

ORGANOMETALLICS, 1995, 14 (06) :2618-2620

[7] ORGANIC-INORGANIC HYBRID SILICA - CHEMICAL-REACTIVITY AS A TOOL FOR STUDYING THE SOLID ARRANGEMENT AS A FUNCTION OF MOLECULAR-STRUCTURE [J].

CERVEAU, G ;

CORRIU, RJP ;

LEPEYTRE, C .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (05) :793-795

[8]

Corriu R. J. P., 1989, Organic Silicon Compounds, P305, DOI DOI 10.1002/0470025107.CH4

[9]

Cotton F.A., 1988, Advanced Inorganic Chemistry

[10] PREPARATION OF ORGANOSILICON DERIVATIVES OF COBALT-COMPLEXED BUT-2-YNE-1,4-DIOL - X-RAY CRYSTAL-STRUCTURE OF [CO2(CO)5(PPH3)(MU-C2(CH2)2O2(SIPH2)2O2(CH2)2C2)CO2(CO)5(PPH3)] [J].

CRAGG, RH ;

JEFFERY, JC ;

WENT, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (14) :993-994

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