Iron complexes of the N(CH2CH2S)33- ligand;: a paramagnetic, trigonal bipyramidal Fe(II) CO complex as a chelate ligand

被引：20

作者：

Davies, SC ^{[1
]}

Hughes, DL ^{[1
]}

Richards, RL ^{[1
]}

Sanders, JR ^{[1
]}

机构：

[1] John Innes Ctr Plant Sci Res, Nitrogen Fixat Lab, Norwich NR4 7UH, Norfolk, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a807655c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The paramagnetic complex anions [Fe(NS3)Cl](-) [NS3 = N(CH2CH2S)(3)(3-)] and[Fe(NS3)(CO)]- have been prepared and structurally characterised; with FeCl2, [Fe(NS3)(CO)](-) gives the structurally characterised, linear, paramagnetic cluster complex [Fe{Fe(NS3)(CO)-S,S'}(2)].

引用

页码：2699 / 2700

页数：2

共 12 条

[1] Vanadium complexes of the N(CH2CH2S)(3)(3-)-ligand with co-ligands relevant to nitrogen fixation processes
Davies, SC
Hughes, DL
Janas, Z
Jerzykiewicz, L
Richards, RL
Sanders, JR
Sobota, P
[J]. CHEMICAL COMMUNICATIONS, 1997, (14) : 1261 - 1262
[2] DILWORTH JR, UNPUB
[3] TETRATHIOVANADATE(V) AND TETRATHIORHENATE(VII) - STRUCTURES AND REACTIONS, INCLUDING CHARACTERIZATION OF THE VFE2S4 CORE UNIT
DO, YK
SIMHON, ED
HOLM, RH
[J]. INORGANIC CHEMISTRY, 1985, 24 (26) : 4635 - 4642
[4] Time-resolved binding of carbon monoxide to nitrogenase monitored by stopped-flow infrared spectroscopy
George, SJ
Ashby, GA
Wharton, CW
Thorneley, RNF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (27) : 6450 - 6451
[5] SYNTHETIC ROUTES TO FE2S2, FE3S4, FE4S4, AND FE6S9 CLUSTERS FROM THE COMMON PRECURSOR [FE(SC2H5)4]2- - STRUCTURES AND PROPERTIES OF [FE3S4(SR)4]3- AND [FE6S9(SC2H5)2]4-, EXAMPLES OF THE NEWEST TYPES OF FE-S-SR CLUSTERS
HAGEN, KS
WATSON, AD
HOLM, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (12) : 3905 - 3913
[6] Crystal structure of nitrile hydratase reveals a novel iron centre in a novel fold
Huang, WJ
Jia, J
Cummings, J
Nelson, M
Schneider, G
Lindqvist, Y
[J]. STRUCTURE, 1997, 5 (05) : 691 - 699
[7] Nickel(II) thiolate complex with carbon monoxide and its Fe(II) analog: Synthetic models for CO adducts of nickel-iron-containing enzymes
Nguyen, DH
Hsu, HF
Millar, M
Koch, SA
Achim, C
Bominaar, EL
Munck, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (37) : 8963 - 8964
[8] Pau R. N., 1991, Biology and biochemistry of nitrogen fixation., P37
[9] Synthesis and structure of a trigonal monopyramidal Fe(II) complex and its paramagnetic carbon monoxide derivative
Ray, M
Golombek, AP
Hendrich, MP
Young, VG
Borovik, AS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (25) : 6084 - 6085
[10] Rees D. C., 1993, ADV INORG CHEM, V40, P89

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