Synthesis and electroactivity of pyrrole end-functionalized poly(2-methyl-2-oxazoline)

被引：21

作者：

Cirpan, A

Alkan, S

Toppare, L ^{[1
]}

David, G

Yagci, Y

机构：

[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey

[2] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

[3] Gh Asashi Tech Univ, Dept Macromol, Iasi 6600, Romania

来源：

EUROPEAN POLYMER JOURNAL | 2001年 / 37卷 / 11期

关键词：

macromonomer; pyrrole functionalization; poly(2-methyl-2-oxazoline);

D O I：

10.1016/S0014-3057(01)00103-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly (2-methyl-2-oxazoline) (PMeOZO) with pyrrole end groups was synthesized by cationic ring polymerization of 2-methyl-2-oxazoline initiated by benzyl bromide and subsequent modification of the halide end group. The structure and electroactivity of the macromonomer thus obtained were confirmed by spectral analysis and cyclic voltametry, respectively. The posssibility of chemical and electrochemical graft copolymerization of PMeOZO with pyrrole was also studied. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2225 / 2229

页数：5

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