Synthesis of alkenylene-bridged macrocyclic silsesquioxanes by ruthenium or rhodium-catalyzed ring-closing reactions of bis(allyldimethylsilyl) groups

被引：10

作者：

Wada, K ^{[1
]}

Izuhara, D ^{[1
]}

Yamada, K ^{[1
]}

Shiotsuki, M ^{[1
]}

Kondo, T ^{[1
]}

Mitsudo, T ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 18期

关键词：

D O I：

10.1039/b104086n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel alkenylene-bridged oligosilsesquioxanes composed of half-caged structures with 16- or 17-membered rings as well as a titanium-containing molecule with a twisted 21-membered macrocycle have been synthesized by ruthenium or rhodium-catalyzed ring-closing reactions of silsesquioxanes with bis(allyldimethylsilyl) groups.

引用

页码：1802 / 1803

页数：2

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