X-ray crystallographic characterization of potassium pentaphenyl[60]fullerene

被引：23

作者：

Matsuo, Y ^{[1
]}

Tahara, K ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 08期

关键词：

D O I：

10.1246/cl.2005.1078

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-ray crystal structures of three differently solvated forms of potassium pentaphenyl[60]fullerene, K(C60Ph5)(thf)(3), [K(thf)(6)][C60Ph5], and [K(18-crown-6)(dmf)][C60Ph5], indicate that the potassium cation and the fullerene cyclopentadienide become separated easily by cation solvation, and suggest that a solvent-separated ion pair is responsible for the formation of bilayer vesicles upon dissolution of KC60Ph5 in water.

引用

页码：1078 / 1079

页数：2

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