A porous metal-organic framework with helical chain building units exhibiting facile transition from micro- to meso-porosity

被引：53

作者：

Park, Jinhee ^{[1
]}

Li, Jian-Rong ^{[1
]}

Sanudo, E. Carolina ^{[2
]}

Yuan, Daqiang ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 06期

基金：

美国国家科学基金会;

关键词：

COORDINATION POLYMERS; HYDROGEN STORAGE; SUPRAMOLECULAR ISOMERISM; CONSTRUCTION; DESIGN;

D O I：

10.1039/c1cc16261f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-organic framework (MOF) with helical channels has been constructed by bridging helical chain secondary building units with 2,6-di-p-carboxyphenyl-4,4'-bipyridine ligands. The activated MOF shows permanent porosity and gas adsorption selectivity. Remarkably, the MOF exhibits a facile transition from micro- to meso-porosity.

引用

收藏

页码：883 / 885

页数：3

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