RECENT ADVANCES IN THE STUDY OF MESOPOROUS METAL-ORGANIC FRAMEWORKS

被引:88
作者
Fang, Qian-Rong [1 ]
Makal, Trevor A. [1 ]
Young, Mark D. [1 ]
Zhou, Hong-Cai [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
关键词
ZEOLITIC IMIDAZOLATE FRAMEWORKS; SULFONIC-ACID FUNCTIONALIZATION; MOLECULAR-SIEVES; HYDROGEN STORAGE; GIANT PORES; COORDINATION COPOLYMER; MCM-41-TYPE SILICA; COMBINED ALKYL; DESIGN; CHEMISTRY;
D O I
10.1080/02603594.2010.520254
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Metal-organic frameworks (MOFs), which consist of metal ions or clusters and organic bridging ligands, have recently emerged as an important family of porous materials. In this comment, we discuss the current state of the field pertaining to MOFs with pore sizes between 2 and 50nm, which have great application potential in gas storage, separation, sensor, catalysis, and drug delivery. This review will cover mesoporous MOFs containing 3-D channels, 1-D channels, and large cavities, as well as those based on supramolecular templates.
引用
收藏
页码:165 / 195
页数:31
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