RECENT ADVANCES IN THE STUDY OF MESOPOROUS METAL-ORGANIC FRAMEWORKS

被引：88

作者：

Fang, Qian-Rong ^{[1
]}

Makal, Trevor A. ^{[1
]}

Young, Mark D. ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

COMMENTS ON INORGANIC CHEMISTRY | 2010年 / 31卷 / 5-6期

关键词：

ZEOLITIC IMIDAZOLATE FRAMEWORKS; SULFONIC-ACID FUNCTIONALIZATION; MOLECULAR-SIEVES; HYDROGEN STORAGE; GIANT PORES; COORDINATION COPOLYMER; MCM-41-TYPE SILICA; COMBINED ALKYL; DESIGN; CHEMISTRY;

D O I：

10.1080/02603594.2010.520254

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-organic frameworks (MOFs), which consist of metal ions or clusters and organic bridging ligands, have recently emerged as an important family of porous materials. In this comment, we discuss the current state of the field pertaining to MOFs with pore sizes between 2 and 50nm, which have great application potential in gas storage, separation, sensor, catalysis, and drug delivery. This review will cover mesoporous MOFs containing 3-D channels, 1-D channels, and large cavities, as well as those based on supramolecular templates.

引用

页码：165 / 195

页数：31

共 116 条

[21] Ordered porous materials for emerging applications [J].

Davis, ME .

NATURE, 2002, 417 (6891) :813-821

[22] Rhodamine fluorescent dimers adsorbed on the porous surface of silica gels [J].

del Monte, F ;

Mackenzie, JD ;

Levy, D .

LANGMUIR, 2000, 16 (19) :7377-7382

[23] Combined alkyl and sulfonic acid functionalization of MCM-41-type silica -: Part 1.: Synthesis and characterization [J].

Díaz, I ;

Márquez-Alvarez, C ;

Mohino, F ;

Pérez-Pariente, J ;

Sastre, E .

JOURNAL OF CATALYSIS, 2000, 193 (02) :283-294

[24] Combined alkyl and sulfonic acid functionalization of MCM-41-Type silica -: Part 2.: Esterification of glycerol with fatty acids [J].

Díaz, I ;

Márquez-Alvarez, C ;

Mohino, F ;

Pérez-Pariente, J ;

Sastre, E .

JOURNAL OF CATALYSIS, 2000, 193 (02) :295-302

[25] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[26] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[27] Mesoporous metal-organic framework with rare etb topology for hydrogen storage and dye assembly [J].

Fang, Qian-Rong ;

Zhu, Guang-Shan ;

Jin, Zhao ;

Ji, Yan-Yan ;

Ye, Jun-Wei ;

Xue, Ming ;

Yang, Hua ;

Wang, Yue ;

Qiu, Shi-Lun .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (35) :6638-6642

[28] A hybrid solid with giant pores prepared by a combination of targeted chemistry, simulation, and powder diffraction [J].

Férey, G ;

Serre, C ;

Mellot-Draznieks, C ;

Millange, F ;

Surblé, S ;

Dutour, J ;

Margiolaki, I .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) :6296-6301

[29] A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F ;

Dutour, J ;

Surblé, S ;

Margiolaki, I .

SCIENCE, 2005, 309 (5743) :2040-2042

[30] Crystallized frameworks with giant pores:: Are there limits to the possible? [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225

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