Spoilt for choice: assessing phase behavior models for the evolution of homochirality

被引：85

作者：

Blackmond, Donna G. ^{[1
]}

Klussmann, Martin

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn & Chem Technol, London SW7 2AZ, England

[3] Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 39期

关键词：

D O I：

10.1039/b709314b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The observation of single chirality in biological systems has intrigued scientists for more than one hundred years. Here we discuss several recent experimental studies showing amplification of enantiomeric excess based on amino acid phase behavior. Comparing observations of solution solid and gas-solid phase transitions highlights the underlying fundamental physical chemistry principles that rationalize the observed enantioenrichment in both cases.

引用

页码：3990 / 3996

页数：7

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