Lithiated cobaltates for lithium-ion batteries - Structure, morphology and electrochemistry of oxides grown by solid-state reaction, wet chemistry and film deposition

被引:34
作者
Julien, C [1 ]
Gastro-Garcia, S [1 ]
机构
[1] Univ Paris 06, Lab Milieux Desordonnes & Heterogenes, UMR 7603, F-75252 Paris 05, France
关键词
cobaltate; lithium-ion battery; solid-state reaction;
D O I
10.1016/S0378-7753(01)00676-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We present the structural (XRD and Raman) and electrochemical properties of various oxides of the cobaltate family (with the alpha -NaFeO2-type structure) grown by solid-state reaction, wet chemistry and film deposition techniques. It is shown that synthesis greatly affects the electrochemistry and cycle life characteristics of these layer structured cathode materials. HT-LiCoO2, LT-LiCoO2, doped LiCo1-yAlyO2 and LiCoO2 films are investigated. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:290 / 293
页数:4
相关论文
共 13 条
  • [11] COMPARATIVE-STUDY OF LICOO2, LINI1/2CO1/2O2 AND LINIO2 FOR 4-VOLT SECONDARY LITHIUM CELLS
    OHZUKU, T
    UEDA, A
    NAGAYAMA, M
    IWAKOSHI, Y
    KOMORI, H
    [J]. ELECTROCHIMICA ACTA, 1993, 38 (09) : 1159 - 1167
  • [12] LITHIUM-ION RECHARGEABLE BATTERIES WITH LICOO2 AND CARBON ELECTRODES - THE LICOO2 C SYSTEM
    OZAWA, K
    [J]. SOLID STATE IONICS, 1994, 69 (3-4) : 212 - 221
  • [13] LITHIUM INSERTION INTO MANGANESE SPINELS
    THACKERAY, MM
    DAVID, WIF
    BRUCE, PG
    GOODENOUGH, JB
    [J]. MATERIALS RESEARCH BULLETIN, 1983, 18 (04) : 461 - 472