A self-assembled monolayers assisted solid-state conversion of boehmite particles to aluminum oxide film

被引:14
作者
Sakuragi, Naoko [1 ]
Yamamoto, Shintaro [1 ]
Koide, Yoshihiro [1 ]
机构
[1] Kanagawa Univ, Fac Engn, Dept Mat & Life Chem, Kanagawa 2218686, Japan
关键词
D O I
10.1021/ja068981o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An aluminum oxide coating film is prepared for the first time by a solid-state conversion of boehmite (AlOOH center dot n H2O) particles, which are covalently attached on self-assembled monolayers (SAMs) of 11-mercaptoundecanoic acid (MUA) built on Au layer. The particles held on MUA SAMs are subject to sintering at elevated temperatures to fuse into monolithic film. X-ray photoelectron spectroscopy confirmed the existence of the hexacoordinate Al atoms. Fabrication steps are monitored by atomic force microscopy.
引用
收藏
页码:10048 / +
页数:3
相关论文
共 25 条
[1]  
[Anonymous], 2003, INTERLAYER DIELECTRI
[2]  
AUCIELLO O, 2005, APPL PHYS LETT, V86
[3]   ESCA studies of the coordination state of aluminium in oxide environments [J].
Barr, TL ;
Seal, S ;
Wozniak, K ;
Klinowski, J .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1997, 93 (01) :181-186
[4]  
CAI SH, 2003, PHYS REV B, V67
[5]   Aqueous synthesis of water-soluble alumoxanes: Environmentally benign precursors to alumina and aluminum-based ceramics [J].
Callender, RL ;
Harlan, CJ ;
Shapiro, NM ;
Jones, CD ;
Callahan, DL ;
Wiesner, MR ;
MacQueen, DB ;
Cook, R ;
Barron, AR .
CHEMISTRY OF MATERIALS, 1997, 9 (11) :2418-2433
[6]   MICROSTRUCTURES AND MECHANICAL-PROPERTIES OF THIN-FILMS OF ALUMINUM-OXIDE [J].
CHOU, TC ;
NIEH, TG ;
MCADAMS, SD ;
PHARR, GM .
SCRIPTA METALLURGICA ET MATERIALIA, 1991, 25 (10) :2203-2208
[7]  
CLARK DE, 1984, ULTRASTRUCTURE PROCE, P126
[8]   Well-defined carboxyl-terminated alkyl monolayers grafted onto H-Si(111): Packing density from a combined AFM and quantitative IR study [J].
Faucheux, A ;
Gouget-Laemmel, AC ;
de Villeneuve, CH ;
Boukherroub, R ;
Ozanam, F ;
Allongue, P ;
Chazalviel, JN .
LANGMUIR, 2006, 22 (01) :153-162
[9]   Low-temperature Al2O3 atomic layer deposition [J].
Groner, MD ;
Fabreguette, FH ;
Elam, JW ;
George, SM .
CHEMISTRY OF MATERIALS, 2004, 16 (04) :639-645
[10]   Structural characteristics of Al2O3 thin films prepared by spray pyrolysis [J].
Guzmán-Mendoza, J ;
García-Hipólito, M ;
Aguilar-Frutis, M ;
Falcony-Guajardo, CF .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2001, 13 (50) :L955-L959