Localized charge transfer in a molecularly doped conducting polymer

被引：156

作者：

Aziz, Emad E.

Vollmer, Antje

Eisebitt, Stefan

Eberhardt, Wolfgang

Pingel, Patrick

Neher, Dieter

Koch, Norbert

机构：

[1] Humboldt Univ, Inst Phys, D-12489 Berlin, Germany

[2] BESSY, D-12489 Berlin, Germany

[3] Univ Potsdam, Inst Phys, D-14469 Potsdam, Germany

来源：

ADVANCED MATERIALS | 2007年 / 19卷 / 20期

关键词：

D O I：

10.1002/adma.200700926

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular-acceptor doping of polythiophene results in high conductivity, ca. 1 S cm(-1), in solution-processed thin films. Charge-transfer complex formation leads to new hybrid orbitals (see figure), which are derived from the highest occupied level of the donor (polythiophene) and the lowest unoccupied level of the acceptor (tetrafluorotetracyanoquinodimethane).

引用

页码：3257 / +

页数：5

共 38 条

[31] A polymer/semiconductor write-once read-many-times memory
Möller, S
Perlov, C
Jackson, W
Taussig, C
Forrest, SR
[J]. NATURE, 2003, 426 (6963) : 166 - 169
[32] LOCALIZATION AND ITS ABSENCE - A NEW METALLIC STATE FOR CONDUCTING POLYMERS
PHILLIPS, P
WU, HL
[J]. SCIENCE, 1991, 252 (5014) : 1805 - 1812
[33] High-resolution inkjet printing of all-polymer transistor circuits
Sirringhaus, H
Kawase, T
Friend, RH
Shimoda, T
Inbasekaran, M
Wu, W
Woo, EP
[J]. SCIENCE, 2000, 290 (5499) : 2123 - 2126
[34] Calculations of near-edge x-ray-absorption spectra of gas-phase and chemisorbed molecules by means of density-functional and transition-potential theory
Triguero, L
Pettersson, LGM
Agren, H
[J]. PHYSICAL REVIEW B, 1998, 58 (12): : 8097 - 8110
[35] MO and DFT approaches to the calculation of X-ray absorption/emission spectra of nitrogen atom adsorbed on Cu(100)
Triguero, L
Pettersson, LGM
[J]. SURFACE SCIENCE, 1998, 398 (1-2) : 70 - 83
[36] INFLUENCE OF AN IMPROVED LOCAL-SPIN-DENSITY CORRELATION-ENERGY FUNCTIONAL ON THE COHESIVE ENERGY OF ALKALI-METALS
VOSKO, SH
WILK, L
[J]. PHYSICAL REVIEW B, 1980, 22 (08): : 3812 - 3815
[37] TRANSPORT AND EPR STUDIES OF POLYANILINE - A QUASI-ONE-DIMENSIONAL CONDUCTOR WITH 3-DIMENSIONAL METALLIC STATES
WANG, ZH
SCHERR, EM
MACDIARMID, AG
EPSTEIN, AJ
[J]. PHYSICAL REVIEW B, 1992, 45 (08): : 4190 - 4202
[38] Guided growth of nanoscale conducting polymer structures on surface-functionalized nanopatterns
Woodson, M
Liu, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (11) : 3760 - 3763

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