Catalytic oxidation of saturated C-H bonds by tetrabutylammonium periodate and manganese porphyrins

被引：16

作者：

Mohajer, D ^{[1
]}

Bagherzadeh, M ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Shiraz 71454, Iran

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1998年 / 09期

关键词：

D O I：

10.1039/a800216i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Arylalkanes and cycloalkanes are oxidized to their corresponding alcohols and ketones with tetra-n-butylammonium periodate in the presence of manganese(III) porphyrin catalysts and imidazole in CH2Cl2, with low to high yields and moderate to high selectivities at ambient temperature.

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页码：556 / 557

页数：3

相关论文

共 22 条

[1]

[Anonymous], CYTOCHROME P 450 MEC

[2] MECHANISM OF MANGANESE PORPHYRIN-CATALYZED OXIDATION OF ALKENES - ROLE OF MANGANESE(IV) OXO SPECIES [J].

ARASASINGHAM, RD ;

HE, GX ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) :7985-7991

[3] SELECTIVE INTERMOLECULAR CARBON-HYDROGEN BOND ACTIVATION BY SYNTHETIC METAL-COMPLEXES IN HOMOGENEOUS SOLUTION [J].

ARNDTSEN, BA ;

BERGMAN, RG ;

MOBLEY, TA ;

PETERSON, TH .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (03) :154-162

[4] THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS - GIF CHEMISTRY [J].

BARTON, DHR ;

DOLLER, D .

ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (11) :504-512

[5] Shape selective epoxidation of alkenes by metalloporphyrin-dendrimers [J].

Bhyrappa, P ;

Young, JK ;

Moore, JS ;

Suslick, KS .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 113 (1-2) :109-116

[6] Aerobic oxidation of hydrocarbons catalyzed by electronegative iron salen complexes [J].

Bottcher, A ;

Grinstaff, MW ;

Labinger, JA ;

Gray, HB .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 113 (1-2) :191-200

[7] REGIOSELECTIVE AND ENANTIOSELECTIVE EPOXIDATION CATALYZED BY METALLOPORPHYRINS [J].

COLLMAN, JP ;

ZHANG, XM ;

LEE, VJ ;

UFFELMAN, ES ;

BRAUMAN, JI .

SCIENCE, 1993, 261 (5127) :1404-1411

[8] Polyhaloporphyrins: Unusual ligands for metals and metal-catalyzed oxidations [J].

Dolphin, D ;

Traylor, TG ;

Xie, LY .

ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (06) :251-259

[9] State of the art in the development of biomimetic oxidation catalysts [J].

Gonsalves, AMDR ;

Pereira, MM .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 113 (1-2) :209-221

[10] HYDROCARBON OXIDATIONS WITH OXOMETALLOPORPHINATES - ISOLATION AND REACTIONS OF A (PORPHINATO)MANGANESE(V) COMPLEX [J].

GROVES, JT ;

KRUPER, WJ ;

HAUSHALTER, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (20) :6375-6377