Catalytic oxidation of saturated C-H bonds by tetrabutylammonium periodate and manganese porphyrins

被引：16

作者：

Mohajer, D ^{[1
]}

Bagherzadeh, M ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Shiraz 71454, Iran

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1998年 / 09期

关键词：

D O I：

10.1039/a800216i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Arylalkanes and cycloalkanes are oxidized to their corresponding alcohols and ketones with tetra-n-butylammonium periodate in the presence of manganese(III) porphyrin catalysts and imidazole in CH2Cl2, with low to high yields and moderate to high selectivities at ambient temperature.

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收藏

页码：556 / 557

页数：3

相关论文

共 22 条

[11]

Hill C. L., 1989, ACTIVATION FUNCTIONA

[12] ALKANE ACTIVATION AND FUNCTIONALIZATION UNDER MILD CONDITIONS BY A HOMOGENEOUS MANGANESE(III) PORPHYRIN-IODOSYLBENZENE OXIDIZING SYSTEM [J].

HILL, CL ;

SCHARDT, BC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (20) :6374-6375

[13] Photocatalytic oxidation of cyclohexane by (nBu(4)N)(4)W10O32/Fe(II) porphyrins integrated systems [J].

Maldotti, A ;

Molinari, A ;

Bergamini, P ;

Amadelli, R ;

Battioni, P ;

Mansuy, D .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 113 (1-2) :147-157

[14] ACTIVATION OF ALKANES - THE BIOMIMETIC APPROACH [J].

MANSUY, D .

COORDINATION CHEMISTRY REVIEWS, 1993, 125 (1-2) :129-141

[15] CYTOCHROME-P-450 AND SYNTHETIC MODELS [J].

MANSUY, D .

PURE AND APPLIED CHEMISTRY, 1987, 59 (06) :759-770

[16]

MEUNIER B, 1986, B SOC CHIM FR, P578

[17] METALLOPORPHYRINS AS VERSATILE CATALYSTS FOR OXIDATION REACTIONS AND OXIDATIVE DNA CLEAVAGE [J].

MEUNIER, B .

CHEMICAL REVIEWS, 1992, 92 (06) :1411-1456

[18] EFFICIENT OLEFIN EPOXIDATION WITH TETRABUTYLAMMONIUM PERIODATE CATALYZED BY MANGANESE PORPHYRIN IN THE PRESENCE OF IMIDAZOLE [J].

MOHAJER, D ;

TANGESTANINEJAD, S .

TETRAHEDRON LETTERS, 1994, 35 (06) :945-948

[19]

PARSHALL GW, 1992, HOMOGENOUS CATALYSIS, pCH10

[20] STUDY OF (TETRAPHENYLPORPHINATO)MANGANESE(III)-CATALYZED EPOXIDATION AND DEMETHYLATION USING PARA-CYANO-N,N-DIMETHYLANILINE N-OXIDE AS OXYGEN DONOR IN A HOMOGENEOUS SYSTEM - KINETICS, RADIOCHEMICAL LIGATION STUDIES, AND REACTION-MECHANISM FOR A MODEL OF CYTOCHROME-P-450 [J].

POWELL, MF ;

PAI, EF ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (11) :3277-3285