Stereoselective synthesis of the C- and CD-ring systems of hemibrevetoxin B

被引：51

作者：

Nakata, T

Nomura, S

Matsukura, H

Morimoto, M

机构：

[1] Inst. of Phys. and Chemical Research, Wako-shi, Saitama

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 02期

基金：

日本科学技术振兴机构;

关键词：

D O I：

10.1016/0040-4039(95)02132-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 7, 7-membered CD ring system of hemibrevetoxin B was stereoselectively synthesized. The crucial steps involve the Sharpless asymmetric epoxidation, cyclization to the 6-membered ether, and double rearrangement of the 6, 6-membered bicyclic ether with the simultaneous ring expansion.

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页码：217 / 220

页数：4

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