Symmetry Switch of Cobalt Ferrocyanide Framework by Alkaline Cation Exchange

被引:69
作者
Matsuda, Tomoyuki [1 ]
Kim, Jungeun [2 ]
Moritomo, Yutaka [1 ]
机构
[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan
[2] JASRI SPring 8, Sayo, Hyogo 6795198, Japan
关键词
PRUSSIAN BLUE ANALOGS; MAGNETIC-ORDERING TEMPERATURE; MOLECULE-BASED MAGNET; ROOM-TEMPERATURE; COORDINATION POLYMERS; POLE INVERSION; IRON CYANIDE; DEGREES-C; NI; HEXACYANOFERRATE;
D O I
10.1021/ja105482k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We observed a reversible symmetry switch of a cobalt ferrocyanide framework by the alkaline cation exchange and resultant control of the optical properties at room temperature.
引用
收藏
页码:12206 / 12207
页数:2
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