Spatiotemporal propagation of a non-linear electrochemical reaction over an iron electrode

被引:13
作者
Nakabayashi, S [1 ]
Baba, R
Shiomi, Y
机构
[1] Saitama Univ, Fac Sci, Dept Chem, Urawa, Saitama 338, Japan
[2] Tokyo Univ Mercantile Marine, Dept Marine Syst Engn, Tokyo 135, Japan
关键词
D O I
10.1016/S0009-2614(98)00202-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Propagation of the reaction rent of oxide formation and reduction along an iron electrode has been investigated when a self-sustained non-linear current oscillation is proceeding, It has been observed that a resistance inserted between the electrode and the potential source changes the oscillation waveform and the propagation speed of the reduction, This finding shows a coupling between the ohmic potential drop in the solution and the reaction propagation along the electrode. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:632 / 638
页数:7
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