A novel chiral porous metal-organic framework: asymmetric ring opening reaction of epoxide with amine in the chiral open space

被引：175

作者：

Tanaka, Koichi ^{[1
]}

Oda, Shinji ^{[1
]}

Shiro, Motoo ^{[2
]}

机构：

[1] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Osaka 5648680, Japan

[2] Rigaku Xray Lab, Tokyo 1968666, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 07期

关键词：

D O I：

10.1039/b714083e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel chiral metal-organic framework, [Cu-2(5,5'-BDA)(2)] was synthesized by treating chiral 2,2'- dihydroxy-1,1'-binaphthalene-5,5'-dicarboxylic acid (5,5'-H(2)BDA) with a Cu(II) ion, in which the asymmetric ring opening reaction of an epoxide with amine proceeds efficiently under solvent-free conditions.

引用

页码：820 / 822

页数：3

共 34 条

[1] Probing the Lewis acidity and catalytic activity of the metal-organic framework [Cu3(btc)2] (BTC = benzene-1,3,5-tricarboxylate) [J].

Alaerts, Luc ;

Seguin, Etienne ;

Poelman, Hilde ;

Thibault-Starzyk, Frederic ;

Jacobs, Pierre A. ;

De Vos, Dirk E. .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (28) :7353-7363

[2] Permanent microporosity and enantioselective sorption in a chiral open framework [J].

Bradshaw, D ;

Prior, TJ ;

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114

[3] A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation [J].

Cho, So-Hye ;

Ma, Baoqing ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. ;

Albrecht-Schmitt, Thomas E. .

CHEMICAL COMMUNICATIONS, 2006, (24) :2563-2565

[4] Homochiral 3D open frameworks assembled from 1-and 2-D coordination polymers [J].

Cui, Y ;

Ngo, HL ;

White, PS ;

Lin, WB .

CHEMICAL COMMUNICATIONS, 2003, (08) :994-995

[5]

Cui Y, 2002, ANGEW CHEM INT EDIT, V41, P1159, DOI 10.1002/1521-3773(20020402)41:7<1159::AID-ANIE1159>3.0.CO

[6]

2-5

[7] A homochiral metal-organic material with permanent porosity, enantioselective sorption properties, and catalytic activity [J].

Dybtsev, DN ;

Nuzhdin, AL ;

Chun, H ;

Bryliakov, KP ;

Talsi, EP ;

Fedin, VP ;

Kim, K .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :916-920

[8] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[9] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[10] Chiral porous solids based on lamellar lanthanide phosphonates [J].

Evans, OR ;

Ngo, HL ;

Lin, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) :10395-10396

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