TiCl4-catalyzed intermolecular hydroamination reactions

被引：102

作者：

Ackermann, L ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 22期

关键词：

D O I：

10.1021/om034143g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A user-friendly procedure for intermolecular hydroamination reactions is presented which employs inexpensive and readily available TiCl4. Through addition of (BuNH2)-Bu-t, a novel catalytic system is generated which enables the efficient conversion of aminoallenes, as well as variously substituted internal and terminal alkynes.

引用

页码：4367 / 4368

页数：2

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