Solid-phase extraction versus solid-phase microextraction for the determination of chlorinated paraffins in water using gas chromatography - negative chemical ionisation mass spectrometry

被引：52

作者：

Castells, P ^{[1
]}

Santos, FJ ^{[1
]}

Galceran, MT ^{[1
]}

机构：

[1] Univ Barcelona, Dept Quim Analit, E-08028 Barcelona, Spain

来源：

JOURNAL OF CHROMATOGRAPHY A | 2004年 / 1025卷 / 02期

关键词：

water analysis; solid-phase extraction; solid-phase microextraction; paraffins; chlorinated;

D O I：

10.1016/j.chroma.2003.10.069

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Solid-phase extraction (SPE) and solid-phase microextraction (SPME) were evaluated for the analysis of short-chain chlorinated paraffins (SCCPs) in water samples using gas chromatography coupled to negative chemical ionisation mass spectrometry (GC-NCI-MS). For SPE optimisation, four commercially available SPE cartridges were tested and several SPE parameters, such as the elution solvent, elution volume and breakthrough volume were studied. The best results were obtained with Varian Bond Elut-C-18. In order to achieve a high selectivity in the determination of SCCPs, GC-NCI-MS was used. Quality parameters of the optimised SPE and SPME procedures were determined, and the best results were obtained for the SPE/GC-NCI-MS method with LODs of 5 and 20 ng l(-1) for tap and river water, respectively. This method was successfully applied to the analysis of SCCPs in river water samples at concentrations below the mug l(-1) level. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：157 / 162

页数：6

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