Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals

被引：50

作者：

Chernikova, Elena ^{[1
]}

Golubev, Vladimir ^{[1
]}

Filippov, Anatoly ^{[1
]}

Lin, Ching Yeh ^{[2
]}

Coote, Michelle L. ^{[2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Polymer Dept, Moscow 119991, Russia

[2] Australian Natl Univ, Res Sch Chem, ARC Ctr Excellence Free Rad Chem & Biotechnol, Canberra, ACT 0200, Australia

来源：

POLYMER CHEMISTRY | 2010年 / 1卷 / 09期

基金：

俄罗斯基础研究基金会; 澳大利亚研究理事会;

关键词：

IONIZATION MASS-SPECTROMETRY; THIOKETONE-MEDIATED POLYMERIZATION; SIZE-EXCLUSION CHROMATOGRAPHY; CHAIN-TRANSFER POLYMERIZATION; SEC-ESI-MS; AB-INITIO; BUTYL ACRYLATE; EQUILIBRIUM; MECHANISM; KINETICS;

D O I：

10.1039/c0py00245c

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Spin traps have been used to obtain the first direct experimental determination of the addition (5 x 10(6) L mol(-1) s(-1)), fragmentation (8 x 10(-3) s(-1)) and self-termination (6.5 x 10(2) L mol(-1) s(-1)) rate coefficients in RAFT polymerization using the interaction of a tert-butyl radical with tert-butyl dithiobenzoate at ambient temperature as a model reaction.

引用

页码：1437 / 1440

页数：4

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