One and two-component hard-core plasmas

被引:48
作者
Netz, RR [1 ]
Orland, H
机构
[1] Max Planck Inst Kolloid & Grenzflachenforsch, D-14424 Potsdam, Germany
[2] CEA Saclay, Serv Phys Theor, F-91191 Gif Sur Yvette, France
关键词
D O I
10.1007/s101890050008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A field theory is presented for particles which interact via Coulomb and hard-core potentials, as relevant for classical plasmas, electrolytes, and charged colloidal solutions. We apply the method to the one-component plasma with hard cores (OCPHC), consisting of identical particles of fixed charge and diameter in a neutralizing background, and the symmetric two-component plasma with hard cores (TCPHC), consisting of equal numbers of positively and negatively charged particles of identical size. We obtain the first fea coefficients of a systematic low-density expansion of the free energy for both models exactly and in closed form. The OCPHC coefficients go over to the classical Abe result in the high-charge (or small hard-core diameter) limit. The TCPHC, on the other hand, exhibits diverging coefficients in the high-charge limit, which is due to the formation of strongly bound ion-pairs.
引用
收藏
页码:67 / 73
页数:7
相关论文
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