Electronic structure of GeO2-passivated interfaces of (100)Ge with Al2O3 and HfO2

被引:70
作者
Afanas'ev, V. V. [1 ]
Stesmans, A. [1 ]
Delabie, A. [2 ]
Bellenger, F. [2 ]
Houssa, M. [2 ]
Meuris, M. [2 ]
机构
[1] Katholieke Univ Leuven, Dept Phys & Astron, B-3001 Heverlee, Belgium
[2] IMEC, B-3001 Louvain, Belgium
关键词
D O I
10.1063/1.2831668
中图分类号
O59 [应用物理学];
学科分类号
摘要
Analysis of internal photoemission and photoconductivity in Ge/thermal germanium oxide/high-dielectric constant oxide (HfO2,Al2O3) structures reveals that the bandgap of the germanium oxide interlayer is significantly lower (4.3 +/- 0.2 eV) than that of stiochiometric GeO2 (5.4-5.9 eV). As a result, the conduction and valence band offsets at the interface appear to be insufficient to block electron and hole injection leading to significant charge trapping in the GeOx/high-kappa oxide stack. Formation of a hydroxyl-rich Ge oxide phase is suggested to be responsible for the modification of the oxide properties. (c) 2008 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 14 条
[1]   Spectroscopy of electron states at interfaces of (100)Ge with high-κ insulators [J].
Afanas'ev, V. V. ;
Stesmans, A. .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2006, 9 (4-5) :764-771
[2]   Internal photoemission of electrons and holes from (100)Si into HfO2 [J].
Afanas'ev, VV ;
Stesmans, A ;
Chen, F ;
Shi, X ;
Campbell, SA .
APPLIED PHYSICS LETTERS, 2002, 81 (06) :1053-1055
[3]   Band alignments in metal-oxide-silicon structures with atomic-layer deposited Al2O3 and ZrO2 [J].
Afanas'ev, VV ;
Houssa, M ;
Stesmans, A ;
Heyns, MM .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (05) :3079-3084
[4]  
Bohm H. F., 1972, Journal of Non-Crystalline Solids, V7, P192, DOI 10.1016/0022-3093(72)90289-X
[5]   Effective electrical passivation of Ge(100) for high-k gate dielectric layers using germanium oxide [J].
Delabie, Annelies ;
Bellenger, Florence ;
Houssa, Michel ;
Conard, Thierry ;
Van Elshocht, Sven ;
Caymax, Matty ;
Heyns, Marc ;
Meuris, Marc .
APPLIED PHYSICS LETTERS, 2007, 91 (08)
[6]  
Kasumov Yu. N., 1988, SOV J PHYS CHEM MECH, V7, P78
[7]   Isochronal annealing of BG written either in H2-loaded, UV hypersensitized or in OH-flooded standard telecommunication fibers using ArF laser [J].
Lancry, M ;
Niay, P ;
Douay, M ;
Depecker, C ;
Cordier, P ;
Poumellec, B .
JOURNAL OF LIGHTWAVE TECHNOLOGY, 2006, 24 (03) :1376-1387
[8]   Physical properties of thin GeO2 films produced by reactive DC magnetron sputtering [J].
Lange, T ;
Njoroge, W ;
Weis, H ;
Beckers, M ;
Wuttig, M .
THIN SOLID FILMS, 2000, 365 (01) :82-89
[9]   Internal photoemission and photoconduction on GeO2/Ge films [J].
Oishi, K ;
Matsuo, Y .
THIN SOLID FILMS, 1996, 274 (1-2) :133-137
[10]   Fabrication of GeO2 layers using a divalent Ge precursor [J].
Perego, M. ;
Scarel, G. ;
Fanciulli, M. ;
Fedushkin, I. L. ;
Skatova, A. A. .
APPLIED PHYSICS LETTERS, 2007, 90 (16)