Fabrication of GeO2 layers using a divalent Ge precursor

被引:88
作者
Perego, M.
Scarel, G.
Fanciulli, M.
Fedushkin, I. L.
Skatova, A. A.
机构
[1] CNR, INFM, MDM Natl Lab, I-20041 Agrate Brianza, Italy
[2] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1063/1.2723684
中图分类号
O59 [应用物理学];
学科分类号
摘要
Good quality and perfectly stoichiometric GeO2 layers are promising interlayers to be implemented in alternative devices based on high dielectric constant oxide/Ge(100). In this work, the authors report on the growth by atomic layer deposition of GeO2 films using a divalent Ge precursor combined with O-3. The films are composed of smooth and perfectly stoichiometric GeO2. The contamination level is extremely low. The deposited GeO2 films have a band gap of 5.81 +/- 0.04 eV. The conduction and valence band offsets at the GeO2/Ge heterojunction are found to be 0.6 +/- 0.1 and 4.5 +/- 0.1 eV, respectively.
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页数:3
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