Single-laser-shot-induced complete bidirectional spin transition at room temperature in single crystals of (FeII(pyrazine)(Pt(CN)4))

被引：193

作者：

Cobo, Saioa ^{[1
]}

Ostrovskii, Denis ^{[1
,2
]}

Bonhommeau, Sebastien ^{[1
]}

Vendier, Laure ^{[1
]}

Molnar, Gabor ^{[1
]}

Salmon, Lionel ^{[1
]}

Tanaka, Koichiro ^{[2
]}

Bousseksou, Azzedine ^{[1
]}

机构：

[1] CNRS UPR 8241, Chim Coordinat Lab, F-31077 Toulouse, France

[2] Kyoto Univ, Grad Sch, Dept Phys, Kyoto 6068502, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 28期

关键词：

D O I：

10.1021/ja800878f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of the {Fe-II(pyrazine)[Pt(CN)(4)]} spin crossover complex were synthesized by a slow diffusion method, The crystals exhibit a thermal spin transition around room temperature (298 K), which is accompanied by a 14 K wide hysteresis loop. X-ray single-crystal analysis confirms that this compound crystallizes in the tetragonal P4/mmm space group in both spin states. Within the thermal hysteresis region a complete bidirectional photoconversion was induced between the two phases (high spin low spin) when a short single laser pulse (4 ns, 532 nm) was shined on the sample.

引用

页码：9019 / 9024

页数：6

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