Green polymer chemistry: Microwave-assisted single-step synthesis of various (meth)acrylamides and poly(meth)acrylamides directly from (meth)acrylic acid and amines

被引：36

作者：

Goretzki, C ^{[1
]}

Krlej, A ^{[1
]}

Steffens, C ^{[1
]}

Ritter, H ^{[1
]}

机构：

[1] Univ Dusseldorf, Inst Organ & Makromol Chem, Lehrstuhl 2, D-40225 Dusseldorf, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 03期

关键词：

green chemistry; irradiation; (meth)acrylamides; microwave-assisted synthesis; radical polymerization;

D O I：

10.1002/marc.200300154

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Various (meth)acrylamides were synthesized in good yields directly from (meth)acrylic acid and an amine using microwave irradiation in a solvent free environment. Under the applied conditions the (meth)acrylic function is preserved. Furthermore the addition of an initiator like 2,2'-azoisobutyronitrile (AlBN) to the starting mixture leads directly to poly(meth)acrylamides in a single step.

引用

页码：513 / 516

页数：4

共 14 条

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