Synthesis and crystal structure of a unique and homochiral N,S-bonded N,N′-bis(tert-butanesulfinyl)amidinate rhodium(I) complex

被引：19

作者：

Souers, AJ

Owens, TD

Oliver, AG

Hollander, FJ

Ellman, JA ^{[1
]}

机构：

[1] Univ Calif Berkeley, Ctr New Direct Organ Synth, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Dept Chem, CHEX RAY Facil, Berkeley, CA 94720 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 20期

关键词：

D O I：

10.1021/ic0104205

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel N,N ' -bis(sulfinyl)amidine ligand has been synthesized from optically pure (R)-tert-butanesulfinamide. Deprotonation of this ligand and stirring with (Rh(COD)Cl-2) afford a structurally unique homochiral N,S-bonded metallocycle with rhodium(I). This is the first reported example of a complex involving a bis(sulfinyl)amidinate ligand and any transition metal center.

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页码：5299 / +

页数：4

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