Unprecedented N,S,O co-ordination of the doubly deprotonated anion of N-benzoyl-N′-phenylthiourea (H2L2) bridging two rhodium(I) centres:: crystal structure of the acetone solvate of [(PPh3)2(CO)Rh(μ-L2-κN′:κO,S)Rh(PPh3)(CO)]

被引：48

作者：

Kemp, G

Roodt, A

Purcell, W

Koch, KR

机构：

[1] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa

[2] Univ Cape Town, Dept Chem, ZA-7700 Rondebosch, South Africa

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 23期

关键词：

D O I：

10.1039/a705887j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [Rh(CO)(2)Cl](2) with N-benzoyl-N'-phenylthiourea (H2L2) followed by PPh3 resulted in an unprecedented tridentate(kappa N':kappa O,S) bonding mode of the doubly deprotonated anion of N-benzoyl-N'-phenylthiourea to yield a dinuclear rhodium(I) complex [(PPh3)(2)(CO)Rh(mu-L-2- kappa N':kappa O,S)Rh(PPh3)(CO)].(CH3)(2)CO, the structure of which was determined by X-ray crystallography.

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页码：4481 / 4483

页数：3

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