Ionothermal Synthesis of Polyoxometalates

被引:46
作者
Ahmed, Ejaz [1 ,2 ]
Ruck, Michael [1 ,2 ]
机构
[1] Tech Univ Dresden, Fachrichtung Chem & Lebensmittelchem, D-01062 Dresden, Germany
[2] Max Planck Inst Phys Fester Stoffe, D-01187 Dresden, Germany
关键词
environmentally friendly synthesis; functional materials; ionic liquids; ionothermal synthesis; polyoxometalates; IONIC LIQUIDS; CHEMISTRY; TEMPLATE; CLUSTERS;
D O I
10.1002/anie.201107014
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An emerging approach: In the ionothermal synthesis of transition-metal- oxide clusters an ionic liquid acts as a solvent, structure-directing agent, and charge-compensating species. The method may open new convenient routes for the synthesis of polyoxometalate-based materials. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:308 / 309
页数:2
相关论文
共 22 条
[1]   Homo- and heteroatomic polycations of groups 15 and 16. Recent advances in synthesis and isolation using room temperature ionic liquids [J].
Ahmed, Ejaz ;
Ruck, Michael .
COORDINATION CHEMISTRY REVIEWS, 2011, 255 (23-24) :2892-2903
[2]   Chemistry of polynuclear transition-metal complexes in ionic liquids [J].
Ahmed, Ejaz ;
Ruck, Michael .
DALTON TRANSACTIONS, 2011, 40 (37) :9347-9357
[3]  
Aidoudi FH, 2011, NAT CHEM, V3, P801, DOI [10.1038/nchem.1129, 10.1038/NCHEM.1129]
[4]  
[Anonymous], 2010, ANGEW CHEM INT EDIT, DOI [DOI 10.1002/ANGE.200902483, DOI 10.1002/ange.200902483]
[5]   Ionothermal syntheses of three transition-metal-containing polyoxotungstate hybrids exhibiting the photocatalytic and electrocatalytic properties [J].
Chen, Wei-Lin ;
Chen, Bao-Wang ;
Tan, Hua-Qiao ;
Li, Yang-Guang ;
Wang, Yong-Hui ;
Wang, En-Bo .
JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (02) :310-321
[6]   Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J].
Cooper, ER ;
Andrews, CD ;
Wheatley, PS ;
Webb, PB ;
Wormald, P ;
Morris, RE .
NATURE, 2004, 430 (7003) :1012-1016
[7]   Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications [J].
Dolbecq, Anne ;
Dumas, Eddy ;
Mayer, Cedric R. ;
Mialane, Pierre .
CHEMICAL REVIEWS, 2010, 110 (10) :6009-6048
[8]   Polyoxometalate-Based Metal-Organic Frameworks Assembled under the Ionothermal Conditions [J].
Fu, Hai ;
Li, Yangguang ;
Lu, Ying ;
Chen, Weilin ;
Wu, Qiong ;
Meng, Jingxin ;
Wang, Xiaolan ;
Zhang, Zhiming ;
Wang, Enbo .
CRYSTAL GROWTH & DESIGN, 2011, 11 (02) :458-465
[9]  
Khan MI, 2000, J SOLID STATE CHEM, V152, P105, DOI 10.1006/jssc.2000.8705
[10]   Organic-inorganic composites based on room temperature ionic liquid and 12-phosphotungstic acid salt with high assistant catalysis and proton conductivity [J].
Li, Zhiying ;
Zhang, Qian ;
Liu, Hongtao ;
He, Ping ;
Xu, Xiudong ;
Li, Jinghong .
JOURNAL OF POWER SOURCES, 2006, 158 (01) :103-109