Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

被引：1593

作者：

Dolbecq, Anne ^{[1
]}

Dumas, Eddy ^{[1
]}

Mayer, Cedric R. ^{[1
]}

Mialane, Pierre ^{[1
]}

机构：

[1] Univ Versailles St Quentin Yvelines, Inst Lavoisier Versailles, UMR 8180, F-78035 Versailles, France

来源：

CHEMICAL REVIEWS | 2010年 / 110卷 / 10期

关键词：

NONLINEAR-OPTICAL PROPERTIES; TRANSITION-METAL CLUSTERS; INDIVIDUALLY DISTINGUISHABLE LABELS; BUILDING-BLOCK APPROACH; RAY CRYSTAL-STRUCTURES; CYCLOPENTADIENYLTITANIUM HETEROPOLYTUNGSTATE ANIONS; ORGANOMETALLIC RUTHENIUM(II) COMPLEXES; OXOMOLYBDENUM COORDINATION-COMPOUNDS; ANDERSON-TYPE HETEROPOLYMOLYBDATES; TRANSMISSION ELECTRON-MICROSCOPY;

D O I：

10.1021/cr1000578

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was conducted to investigate the structural diversity and applications of hybrid organic-inorganic polyoxometalate (POM) compounds. These compounds exhibited a significant diversity of sizes, nuclearities, and shapes. They were built from the connection of {MOx} polyhedra, M being a d-block element in high oxidation state. These compounds played a significant role in various areas ranging from catalysis, medicine, electrochemistry, photochromism, to magnetism. This wide range of applications of these organic-inorganic hybrid polyoxometalate compounds was due to the combination of their added value properties. A large variety of organic fragments had also been considered for the functionalization of POMs, while many efforts were devoted to induce and increase a synergy between the two components, such as the organic moiety and the POM.

引用

页码：6009 / 6048

页数：40

共 597 条

[1] Synthesis and spectroscopic characterization of the heterosilylated anions [PW9O34(tBuSiO)3(SiR)]3- (R = -CH3, -CH=CH2, -CH2-CH=CH2, -(CH2)4-CH=CH2) -: X-ray crystal structure of [nBu4N]3[PW9O34(tBuSiO)3(SiCH2-CH=CH2)] [J].

Agustin, D ;

Coelho, C ;

Mazeaud, A ;

Herson, P ;

Proust, A ;

Thouvenot, R .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (12) :2049-2053

[2] Synthesis, characterization and study of the chromogenic properties of the hybrid polyoxometalates [PW11O39(SiR)2O]3-(R = Et, (CH2)nCH=CH2 (n = 0, 1, 4), CH2CH2SiEt3, CH2CH2SiMe2Ph) [J].

Agustin, Dominique ;

Dallery, Jerome ;

Coelho, Cristina ;

Proust, Anna ;

Thouvenot, Rene .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (04) :746-754

[3] Directing organic-inorganic hybrid molecular-assemblies of polyoxometalate crown-ether complexes with supramolecular cations [J].

Akutagawa, Tomoyuki ;

Endo, Daigoro ;

Noro, Shin-Ichiro ;

Cronin, Leroy ;

Nakamura, Takayoshi .

COORDINATION CHEMISTRY REVIEWS, 2007, 251 (21-24) :2547-2561

[4] STM/STS observation of polyoxoanions on HOPG surfaces:: the wheel-shaped [Cu20Cl(OH)24(H2O)12(P8W48O184)]25- and the ball-shaped [{Sn(CH3)2(H2O)}24{Sn(CH3)2}12(A-PW9O34)12]36- [J].

Alam, MS ;

Dremov, V ;

Muller, P ;

Postnikov, AV ;

Mal, SS ;

Hussain, F ;

Kortz, U .

INORGANIC CHEMISTRY, 2006, 45 (07) :2866-2872

[5] CIS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) AND TRANS-DIHALOTETRAKIS(DIMETHYL SULFOXIDE)RUTHENIUM(II) COMPLEXES (RUX2(DMSO)4, X = CL, BR) - SYNTHESIS, STRUCTURE, AND ANTITUMOR-ACTIVITY [J].

ALESSIO, E ;

MESTRONI, G ;

NARDIN, G ;

ATTIA, WM ;

CALLIGARIS, M ;

SAVA, G ;

ZORZET, S .

INORGANIC CHEMISTRY, 1988, 27 (23) :4099-4106

[6] Hybrid organic-inorganic porphyrin-polyoxometalate complexes [J].

Allain, Clemence ;

Favette, Sophie ;

Chamoreau, Lise-Marie ;

Vaissermann, Jacqueline ;

Ruhlmann, Laurent ;

Hasenknopf, Bernold .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (22) :3433-3441

[7] A three-dimensional bimetallic oxide constructed from octamolybdate clusters and copper-ligand cation polymer subunits. A comment on the stability of the octamolybdate isomers [J].

Allis, DG ;

Rarig, RS ;

Burkholder, E ;

Zubieta, J .

JOURNAL OF MOLECULAR STRUCTURE, 2004, 688 (1-3) :11-31

[8] Organic-inorganic hybrids based on polyoxometalates. Part IV: A multinuclear magnetic resonance structural investigation [J].

Alloul, L ;

Ammari, N ;

Mayer, CR ;

Mazeaud, A ;

Thouvenot, R .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1998, 95 (02) :289-294

[9] A pillar-layered three-dimensional open framework constructed from polyoxometalate-supported metal coordination complex layers and bi-supporting polyoxometalate clusters [J].

An, Haiyan ;

Xu, Tieqi ;

Wang, Enbo ;

Meng, Changgong .

INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (12) :1453-1456

[10] Chiral 3D architectures with helical channels constructed from polyoxometalate clusters and copper-amino acid complexes [J].

An, HY ;

Wang, EB ;

Xiao, DR ;

Li, YG ;

Su, ZM ;

Xu, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (06) :904-908

← 1 2 3 4 5 6 7 8 9 10 →