Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications

被引：1593

作者：

Dolbecq, Anne ^{[1
]}

Dumas, Eddy ^{[1
]}

Mayer, Cedric R. ^{[1
]}

Mialane, Pierre ^{[1
]}

机构：

[1] Univ Versailles St Quentin Yvelines, Inst Lavoisier Versailles, UMR 8180, F-78035 Versailles, France

来源：

CHEMICAL REVIEWS | 2010年 / 110卷 / 10期

关键词：

NONLINEAR-OPTICAL PROPERTIES; TRANSITION-METAL CLUSTERS; INDIVIDUALLY DISTINGUISHABLE LABELS; BUILDING-BLOCK APPROACH; RAY CRYSTAL-STRUCTURES; CYCLOPENTADIENYLTITANIUM HETEROPOLYTUNGSTATE ANIONS; ORGANOMETALLIC RUTHENIUM(II) COMPLEXES; OXOMOLYBDENUM COORDINATION-COMPOUNDS; ANDERSON-TYPE HETEROPOLYMOLYBDATES; TRANSMISSION ELECTRON-MICROSCOPY;

D O I：

10.1021/cr1000578

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was conducted to investigate the structural diversity and applications of hybrid organic-inorganic polyoxometalate (POM) compounds. These compounds exhibited a significant diversity of sizes, nuclearities, and shapes. They were built from the connection of {MOx} polyhedra, M being a d-block element in high oxidation state. These compounds played a significant role in various areas ranging from catalysis, medicine, electrochemistry, photochromism, to magnetism. This wide range of applications of these organic-inorganic hybrid polyoxometalate compounds was due to the combination of their added value properties. A large variety of organic fragments had also been considered for the functionalization of POMs, while many efforts were devoted to induce and increase a synergy between the two components, such as the organic moiety and the POM.

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收藏

页码：6009 / 6048

页数：40

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