Molecular markers of anthropogenic activity in sediments of the Havel and Spree Rivers (Germany)

被引：88

作者：

Ricking, M

Schwarzbauer, J

Franke, S

机构：

[1] Free Univ Berlin, Dept Earth Sci, D-12249 Berlin, Germany

[2] Rhein Westfal TH Aachen, Inst Geol & Geochem Petr & Coal, D-52056 Aachen, Germany

[3] Univ Hamburg, Inst Organ Chem, D-20146 Hamburg, Germany

来源：

WATER RESEARCH | 2003年 / 37卷 / 11期

关键词：

aquatic sediments; anthropogenic molecular markers; GC/MS-screening analysis; sewage treatment plant input;

D O I：

10.1016/S0043-1354(03)00078-2

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Detailed gas chromatographic/mass spectrometric analyses have been applied to sediment samples of the Havel and Spree River, tributaries to the Elbe River, in order to identify specific molecular markers of anthropogenic activities. Despite a wide variety of lipophilic organic compounds from diffuse anthropogenic contamination, a local emission of an industrial point source was reflected by specific markers including halogenated compounds and nitrogen containing substances (4-ethyinitrobenzene, formyl piperidine, acetyl piperidine). In addition to well-known anthropogenic markers various new molecular tracers were detected and are discussed, namely plasticizers (alkylsulfonic acid aryl esters, tributyl and tricresyl phosphates), synthetic fragrances (galaxolide, tonalide, 4-oxoisophorone), additives of personal care products (4-methoxycinnamic acid 2-ethylhexyl ester, benzyl benzoate, dibenzyl ether, benzophenone), occurring due to sewage treatment plant input. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：2607 / 2617

页数：11

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