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Catalytic ozonation of azo dye active brilliant red X-3B in water with natural mineral brucite
被引:103
作者:
Dong, Yuming
He, Kun
Zhao, Bo
Yin, Ying
Yin, Lin
Zhang, Aimin
[1
]
机构:
[1] Nanjing Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Mesoscop Chem, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Dept Earth Sci, Nanjing 210093, Peoples R China
基金:
中国国家自然科学基金;
关键词:
azo dye;
catalytic ozonation;
Brucite;
natural mineral;
D O I:
10.1016/j.catcom.2007.01.016
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Natural mineral brucite was used directly in catalytic ozonation of dye wastewater of active brilliant red X-3B. Compared with single ozonation, degradation of X-3B increased from 47% to 89%, and removal rate of COD increased from 9% to 32.5% in catalytic ozonation for 15 min. The catalytic ozonation of X-3B followed a direct oxidization mechanism by ozone molecule, and this was actually a homogeneous catalysis of OH- due to dissolution of Mg(OH)(2) from natural brucite. As a natural mineral catalyst, brucite has supplied an economical and feasible choice for catalytic ozonation of X-3B in industrial wastewater. (c) 2007 Elsevier B.V. All rights reserved.
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页码:1599 / 1603
页数:5
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